The objective of this study was to determine the influence of trace elements in groundwater using
multivariate statistical techniques, principal component analysis (PCA) and cluster analysis.
Thirteen variables of fifteen shallow groundwater samples were analysed using Inductive
Coupled Plasma Mass Spectroscopy (ICP-MS). Five principal components were extracted that
accounted for 88.52% of the total variance in the data set. Principal component 1 was responsible
for 31.58% of the total variance, which was represented by copper, zinc, chromium, nickel and
iron. Principal component 2 explained 49.76% of the total variance and was represented by
nickel, arsenic, manganese and selenium. Principal component 3 was participated by cadmium
and beryllium, while PC 4 has molybdenum and cobalt, respectively. Principal component
5 was represented by lead and selenium. The cluster analysis revealed two distinct groups
of groundwater that are distinguished by different trace elements constituents. These trace
elements were mainly from anthropogenic sources and parent rock materials in the area of study.
Keywords
Anthropogenic sources; Keana; Parent rock; Principal component analysis; Trace elements
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Published by : Thai Society of Higher Education Institutes on Environment Contributions welcome at : http://www.tshe.org/en/
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